120622-61-9Relevant academic research and scientific papers
Palladium-Catalyzed Carbonylation of Allylamines. Synthesis of β,γ-Unsaturated Amides by One-Carbon Homologation of Allylamines
Murahashi, Shun-Ichi,Imada, Yasushi,Nishimura, Koichi
, p. 453 - 464 (2007/10/02)
Palladium-catalyzed carbonylation of allylamines under CO (50 atm) at 110 deg C proceeds highly efficiently to give the correponding β,γ-unsaturated amides.The carbonylation occurs at the less substituted carbon of allyl units to give linear amides with h
Palladium-catalysed Carbonylation of Allylamines
Murahashi, Shun-Ichi,Imada, Yasushi,Nishimura, Koichi
, p. 1578 - 1579 (2007/10/02)
Carbonylation of allylamines proceeds smoothly in the presence of a palladium-phosphine catalyst to give β,γ-unsaturated amides in good yields.
