1206451-32-2Relevant academic research and scientific papers
N-heterocyclic carbene dichotomy in Pd-catalyzed acylation of aryl chlorides via C-H bond functionalization
Flores-Gaspar, Areli,Gutierrez-Bonet, Alvaro,Martin, Ruben
, p. 5234 - 5237,4 (2012/12/12)
The first Pd-catalyzed intramolecular acylation of aryl chlorides via C-H bond functionalization is presented. The method allows for the synthesis of a variety of elusive benzocyclobutenones with a wide range of functional groups and substitution patterns. We demonstrate that a change in the ligand backbone dictates the selectivity pattern.
N-heterocyclic carbene dichotomy in Pd-catalyzed acylation of aryl chlorides via C-H bond functionalization
Flores-Gaspar, Areli,Gutierrez-Bonet, Alvaro,Martin, Ruben
, p. 5234 - 5237 (2013/01/15)
The first Pd-catalyzed intramolecular acylation of aryl chlorides via C-H bond functionalization is presented. The method allows for the synthesis of a variety of elusive benzocyclobutenones with a wide range of functional groups and substitution patterns. We demonstrate that a change in the ligand backbone dictates the selectivity pattern.
