120654-36-6

Upstream product

• 2009-83-8 6-chloro-1-hexanol 
• 100-61-8 N-methylaniline 
• 4286-55-9 1-bromo-6-hexanol 

Downstream Products

• 120654-37-7 6-[methyl(phenyl)amino]hexyl acetate 
• 1262392-80-2 α-(N-methyl-N-(4-(4'-carboxyphenylazo)phenyl)amino)-ω-(4-hydroxylbiphenylene)-hexane 
• 1262392-81-3 α-N-methyl-N-(4-(4'-cyanophenylazo)phenyl)amino-ω-(4-hydroxylbiphenylene)-hexane 
• 1262392-82-4 α-N-methyl-N-(4-(4'-nitrophenylazo)phenyl)amino-ω-(4-hydroxylbiphenylene)-hexane 
• 1262392-79-9 4-(6-(N-methyl(N-phenyl)amino)hexyloxy)biphenyl-4'-ol 
• 155296-41-6 6-(N-methyl-N-phenylamino)hexyl methacrylate 
• 340137-11-3 6-(N-methyl-N-(4-(4'-cyanophenylazo)phenyl)amino)hexyl methacrylate 
• 120654-22-0 4-benzaldehyde 
• 177087-88-6 4-[N-(6-acetoxyhexyl)-N-methylamino]benzyl alcohol 

Relevant academic research and scientific papers

New epoxy-amine oligomers with chromophore-containing dendritic fragments in the side chain and determination of their nonlinear-optical characteristics

New epoxy-amine oligomers with azochromophore-containing dendritic fragments in the side-chain are synthesized and characterized; nonlinear-optical coefficients of the obtained oligomers are equal to 20 pm V-1.

Squaraines as unique reporters for SERRS multiplexing

Modified anilino squaraine dyes provide unique SERRS spectra that can be identified at low concentrations within any mixture of current reporters using longer, biologically compatible wavelengths of excitation. The Royal Society of Chemistry.

Development of new nonlinear optical polymers based on epoxy- amine oligomers with Bi-chromophore fragments in the side chain

For the first time bichromophore nonlinear optically active compounds, 3,5-bis [2- (N-ethyl-4- (4′-nitrophenylazo) anilino) ethoxy] benzyl alcohol, DF1, and 3,5-bis [6- (N-methyl-4- (4′-nitrophenylazo) anilino) hexaoxy] benzyl alcohol, DF2, have been synthesized. The synthesis of the epoxy-amine oligomers containing DF1 and DF2 dendritic fragments in the side chain was preceded by molecular design which demonstrated that the hexyl groups, binding the chromophores to the branching center in DF2, are able to provide greater mobility of the chromophores compared to the ethyl groups in DF1, thus determining the preference of the former from the viewpoint of NLO activity. Bi-chromophore compounds were introduced into the side chain of epoxy amine oligomers using the esterification reaction under mild conditions by the Steglich method. As a result, oligomers OAB-DF1 (Tg = 122 °C) and OAB-DF2 (Tg = 107 °C) were obtained with good yields, the degree of functionalization was 60 mol% and 45 mol%, respectively. The values of the NLO coefficients, d33, were measured by second harmonic generation technique; they are equal to 29 pm/V for OAB-DF1 and 40 pm/V for OAB-DF2.

Synthesis and self-assembling of diblock copolymers containing a side-on liquid crystalline block and a pseudo-stilbene azobenzene block

Liquid crystalline (LC) diblock copolymers containing a side-on LC block and a pseudo-stilbene azobenzene block were synthesized, and their self-assembling in water/tetrahydrofuran (THF) was investigated. Side-on LC monomer 4’’-methylacryloyloxybutyl 2,5-

Photoresponsive diblock copolymers bearing strong push-pull azo chromophores and cholesteryl groups

A series of diblock copolymers bearing strong push-pull azo chromophores and cholesteryl groups on the respective blocks was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The liquid crystal phase structure, microphase-separated morphology, and photoresponsive properties of the block copolymers were investigated by using DSC, POM, AFM, XRD and laser irradiation. The results show that the cholesteryl block (PChEMA) forms smectic-A mesophase and the morphology depends on the length of the azo block (PAzoCN). When the azo block is short, such as PChEMA50-b-PAzoCN 7, no microphase separation can be identified. For PChEMA 50-b-PAzoCN28, PAzoCN appears as the hexagonal-packed nanocylinders embedded in the PChEMA matrix. When the azo block length further increases, the block copolymer PChEMA50-b-PAzoCN73 forms microphase-separated lamellae. The microphase separation shows no obvious restraint on the photoinduced orientation of the azo chromophores, but micron-scale mass transport of the photoresponsive PAzoCN block is inhibited by the phase confinement.

Cobalt-Catalyzed Remote Hydroboration of Alkenyl Amines

We here present a generally applicable cobalt-catalyzed remote hydroboration of alkenyl amines, providing a practical strategy for the preparation of borylamines and aminoalcohols. This method shows broad substrate scope and good functional group tolerance, tolerating a series of alkenyl amines, including alkyl-alkyl amines, alkyl-aryl amines, aryl-aryl amines, and amides. Of note, this protocol is also compatible with a variety of natural products and drug derivatives. Preliminary mechanistic studies suggest that this transformation involves an iterative chain walking and hydroboration sequence.

NITROGEN HETEROAROMATIC CONTAINING AZOBENZENE COMPOUND AND COMPOSITION FOR GREEN HOLOGRAM RECORDING COMPRISING THEREOF

The present invention relates to a nitrogen-containing heteroaromatics-containing azobenzene compound. The present invention relates to a composition for recording a hologram, a hologram recording medium, a hologram recording material using the same, and

AZOBENZEN COMPOUND AND COMPOSITION FOR HOLOGRAM RECORDING COMPRISING THEREOF

The present invention relates to an azobenzene compound, composition for recording hologram including the same, a medium for recording hologram, a hologram recording material using the same, and a method for recording or re-recording hologram. The azobenz

PHOTOISOMERIZABLE DIPHENYLDIACETYLENE-AZOBENZEN MESOGENS AND POLYMERS THERE OF

The present invention relates to an azobenzene compound, a hologram recording composition containing the same, a hologram recording medium, a hologram recording material using the same, and a hologram recording or rewriting method. The azobenzene monomer

Synthesis, self-assembly and characterization of a novel push-pull thiophene-based chromophore on a gold surface

Push-pull chromophores are widely used and investigated due to their intrinsic electro-optical and non-linear optical properties that are suitable for a variety of applications. However, the grafting and the control of self-organization of such derivatives onto surfaces have been less considered although this may enhance the pre-cited properties and/or enlarge the scope of their use. In this work we present the stepwise synthesis of a novel non-charged push-pull chromophore modified with a fleeting thioacetate group, and the study of its self-assembling abilities onto a gold surface. Self-assembled dense monolayer formation is clearly demonstrated by electrochemical, XPS and STM measurements. Besides, associated with good film quality a conducting behavior consistent with the structure of the SAM-organized push-pull is also highlighted.