1206604-35-4Relevant academic research and scientific papers
Radical Cyclizations for the Synthesis of Pyrroloindoles: Progress toward the Flinderoles
Tejeda, Joanne E. Curiel,Landschoot, Bryan K.,Kerr, Michael A.
, p. 2142 - 2145 (2016)
Under the influence of Lewis acid catalysis, donor/acceptor cyclopropanes underwent nucleophilic ring opening by indolines. The resulting N-alkyl indolines bearing a pendant malonyl moiety oxidatively cyclized to 1,2-pyrroloindoles. This method was showcased by the preparation of the skeletal structure of the flinderoles.
Synthesis of enantioenriched allenes from 1,1-cyclopropanediesters
Cerat, Pascal,Gritsch, Philipp J.,Goudreau, Sebastien R.,Charette, Andre B.
supporting information; experimental part, p. 564 - 567 (2010/06/13)
[Chemical equation presented] Highly substituted alienes were obtained by the SN2′ addition of organocuprate reagents on 2-propargyl-1,1-cyclopropanediesters. This new methodology permits the synthesis of highly enantioenriched allenes as the r
