120663-14-1

Basic information

• Product Name: (7R,8R)-8-benzyloxy-7-hydroxy-2-methyl-9-octadecene
• CAS NO: 120663-14-1
• Molecular Weight: 388.634
• Mol File: 120663-14-1.mol

Chemical Properties

• CAS DataBase Reference: (7R,8R)-8-benzyloxy-7-hydroxy-2-methyl-9-octadecene(CAS DataBase Reference)
• NIST Chemistry Reference: (7R,8R)-8-benzyloxy-7-hydroxy-2-methyl-9-octadecene(120663-14-1)
• EPA Substance Registry System: (7R,8R)-8-benzyloxy-7-hydroxy-2-methyl-9-octadecene(120663-14-1)

Safety Data

• Hazardous Substances Data: 120663-14-1(Hazardous Substances Data)

Upstream product

• 101685-73-8 4-C-(5-methylhexyl)-3-O-benzyl-1,2-O-isopropylidene-α-D-xylo-tetrofuranose 
• 105243-04-7 (2S,3R)-2-benzyloxy-3-formyloxy-8-methylnonanal 
• 101685-74-9 4-C-(5-methylhexyl)-3-O-benzyl-D-xylo-tetrofuranose 
• 101685-71-6 4-C-(5-methyl-1-hexenyl)-1,2-O-isopropylidene-α-D-xylo-tetrofuranose 
• 101685-72-7 4-C-(5-methylhexyl)-1,2-O-isopropylidene-α-D-xylo-tetrofuranose 
• 100-44-7 benzyl chloride 
• 60902-45-6 nonyltriphenylphosphonium bromide 
• 70240-41-4 4-methyl-1-pentyltriphenylphopshonium bromide 
• 101685-77-2 Formic acid (E)-(1R,2R)-2-benzyloxy-1-(5-methyl-hexyl)-dodec-3-enyl ester 

Downstream Products

• 105243-14-9 (7R,8R)-(+)-8-hydroxy-7-p-toluenesulfonyloxy-2-methyloctadecane 
• 105243-11-6 (7R,8R)-(+)-7-hydroxy-9-p-toluenesulfonyloxy-2-methyloctadecane 
• 105243-10-5 (7R,8R)-(+)-7-acetoxy-8-p-toluenesulfonyloxy-2-methyloctadecane 
• 120665-38-5 (7R,8R)-8-benzyloxy-7-p-toluenesulfonyloxy-2-methyl-9-octadecane 
• 101685-80-7 (7R,8R)-7-acetoxy-8-benzyloxy-2-methyl-9-octadecene 

Relevant articles and documents

STEREOSELECTIVE SYNTHESIS OF BOTH ENANTIOMERS OF DISPARLURE, THE SEX PHEROMONE OF THE GYPSY MOTH, FROM D-GLUCOSE

1,2-O-Isopropylidene-α-D-xylopentodialdo-1,4-furanose readily avalaible from D-glucose was transformed in two Wittig reactions and glycol cleavage into a (Z) and (E) mixture of (7R,8R)-8-benzyloxy-7-hydroxy-2-methyl-9-octadecenes.From this chiral synthon both enantiomers of disparlure, (7R,8S)-(+)- and (7S,8R)-(-)-7,8-epoxy-2-methyloctadecane were obtained in four and three steps, respectively.