1206732-31-1Relevant articles and documents
Toward the synthesis of brevipolide H
Mohapatra, Debendra K.,Kanikarapu, Suresh,Naidu, P. Ramesh,Yadav, Jhillu S.
supporting information, p. 1041 - 1044 (2015/02/19)
A linear diastereoselective synthesis of C1-C12 fragment of brevipolide H is described. The key reactions include J?rgensen's asymmetric epoxidation, palladium-catalyzed regioselective opening of α,β-unsaturated γ,δ-epoxide, Charette's modified Simmons-Smith cyclopropanation, anti-selective reduction of cyclopropyl containing α,β-unsaturated ketone, Brown allylation, and ring-closing metathesis reaction.
Studies directed toward the first total synthesis of acremodiol and acremonol
Sharma, Gangavaram V.M.,Mallesham, Samala,Chandra Mouli, Chirutha
experimental part, p. 2513 - 2529 (2010/04/03)
Studies directed toward the synthesis of acremodiol and acremonol resulted in the synthesis of two macrodiolides 1, 1a, and 2 besides 3. The attempted synthesis of 1 and 2 confirmed that the absolute stereochemistry defined in the earlier report is incorr
