1206798-35-7Relevant articles and documents
Dendron-anchored organocatalysts: The asymmetric reduction of imines with trichlorosilane, catalysed by an amino acid-derived formamide appended to a dendron
Figlus, Marek,Caldwell, Stuart T.,Walas, Dawid,Yesilbag, Gulen,Cooke, Graeme,Kocovsky, Pavel,Malkov, Andrei V.,Sanyal, Amitav
experimental part, p. 137 - 141 (2010/04/24)
Asymmetrie reduction of ketimines 1a-f with trichlorosilane can be catalysed by the Lewis-basic N-methylvaline-derived formamide anchored to a soluble dendron (lie) with good enan tio selectivity (≤94% ee) and low catalyst loading (typically 5 mol%) at ro