120702-33-2Relevant academic research and scientific papers
Regioselective palladium-catalyzed formate reduction of N-heterocyclic allylic acetates
Cheng, Hsiu-Yi,Sun, Chong-Si,Hou, Duen-Ren
, p. 2674 - 2677 (2007/10/03)
The regioselective palladium-catalyzed formate reduction of allylic acetates in five- to eight-membered heterocycles is reported. Reduction of allylic acetates under mild conditions using allylpalladium chloride dimer, phosphines, and formic acid/triethyl
CATALYTIC INTRAMOLECULAR 2-(4-ALKENYL)ALLYLPALLADIUM INSERTIONS
Oppolzer, Wolfgang,Swenson, Rolf E.,Gaudin, Jean-Marc
, p. 5529 - 5532 (2007/10/02)
Pd(O)-catalyzed cyclizations of 1-acetoxy-2-methylene-6-heptenes(34, 1819) are consistent with a allylpalladium/olefin insertion involving a metal-transfer to the distal alkene terminal.Cyclization 78 exemplifies a new stereocontrolled access to
