1207384-35-7

Upstream product

• 1207384-25-5 (4aS,5S,6S,8aS)-6-(benzyloxy)-5,8a-dimethyl-3-oxo-3,4,4a,5,6,7,8,8a-octahydronaphthalene-2-carbonitrile 
• 547-26-2 (+)-7-epi-α-cyperone 
• 105087-08-9 (1S,2S,4aS,7S,8aS)-1,4a-dimethyl-7-(prop-1-en-2-yl)decahydronaphthalen-2-ol 
• 1207384-26-6 (1R,4aS,4bS,7S,8S,8aS,10aS)-allyl 7-(benzyloxy)-10a-cyano-3-hydroxy-1,4b,8-trimethyl-10-oxo-1,2,4a,4b,5,6,7,8,8a,9,10,10a-dodecahydrophenanthrene-4-carboxylate 

Relevant academic research and scientific papers

Versatile strategy to access tricycles related to quassinoids and triterpenes

[Chemical equaction presented] The reactivity of two new bicyclic cyclohexenones (13 and 27) with several Nazarov reagents is presented. A flexible synthetic strategy is developed and provides access to highly substituted tricycles related to quassinoids

Anionic polycyclization entry to tricycles related to quassinoids and terpenoids: A stereocontrolled total synthesis of (+)-cassaine

A full account of our anionic polycyclization approach to access highly functionalized tricycles related to quassinoids and terpenoids from several optically active bicyclic enone systems and Nazarov reagents is presented. (+)-Carvone is the only chiral s