1207730-45-7

Basic information

• Product Name: 3-O-benzyl-1,2-O-isopropylidene-6-O-(2,4,6-triisopropylbenzoyl)-β-L-idofuranose
• Synonyms: 3-O-benzyl-1,2-O-isopropylidene-6-O-(2,4,6-triisopropylbenzoyl)-β-L-idofuranose
• CAS NO: 1207730-45-7
• Molecular Weight: 540.697
• Mol File: 1207730-45-7.mol

Chemical Properties

• CAS DataBase Reference: 3-O-benzyl-1,2-O-isopropylidene-6-O-(2,4,6-triisopropylbenzoyl)-β-L-idofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-benzyl-1,2-O-isopropylidene-6-O-(2,4,6-triisopropylbenzoyl)-β-L-idofuranose(1207730-45-7)
• EPA Substance Registry System: 3-O-benzyl-1,2-O-isopropylidene-6-O-(2,4,6-triisopropylbenzoyl)-β-L-idofuranose(1207730-45-7)

Safety Data

• Hazardous Substances Data: 1207730-45-7(Hazardous Substances Data)

Upstream product

• 1207730-46-8 5-O-benzoyl-3-O-benzyl-1,2-O-isopropylidene-6-O-(2,4,6-triisopropylbenzoyl)-β-L-idofuranose 

Downstream Products

• 42926-89-6 1,2-O-isopropylidene-3-O-benzyl-α-D-glucofuranose 

Relevant articles and documents

Novel formal synthesis of stereospecifically C-6 deuterated d-glucose employing configurationally stable alkoxymethyllithiums

The synthesis and testing of configurational stability of chirally monodeuterated PMB- and THP-substituted oxymethyllithiums are described. Macroscopically they are configurationally stable up to -35 °C, the limit of their chemical stability, and microscopically even up to 0 °C. Furthermore, THP-protected oxy-[D1]methyllithium has been applied in the formal synthesis of (6R)-[6-D1]-d-glucose (four steps, 40% yield), an example of its use as a homochiral hydroxymethyl synthon.