1207756-45-3Relevant academic research and scientific papers
A multicomponent CuAAC click approach to a library of hybrid polydentate 2-pyridyl-1,2,3-triazole ligands: New building blocks for the generation of metallosupramolecular architectures
Crowley, James D.,Bandeen, Pauline H.
supporting information; experimental part, p. 612 - 623 (2010/04/03)
A one pot, multicomponent CuAAC reaction has been exploited for the safe generation of alkyl, benzyl or aryl linked polydentate pyridyl-1,2,3-triazole ligands from their corresponding halides, sodium azide and alkynes in excellent yields. The ligands have been fully characterised by elemental analysis, HR-ESMS, IR, 1H and 13C NMR and in two cases the structures were confirmed by X-ray crystallography. Additionally, we have examined the Ag(i) coordination chemistry of these ligands and found, using HR-ESMS, 1H NMR, and X-ray crystallography, that both discrete and polymeric metallosupramolecular architectures can be formed. The Royal Society of Chemistry.
