1207873-40-2Relevant academic research and scientific papers
Asymmetric allylation, crotylation, and cinnamylation of N-heteroaryl hydrazones
Feske, Miriam Inbar,Santanilla, Alexander Buitrago,Leighton, James L.
scheme or table, p. 688 - 691 (2010/04/02)
(Chemical Equation Presented) A new class of N-heteroaryl hydrazones has been developed as an alternative to N-acylhydrazones and 2-amlnophenol-derlved lmlnes In asymmetric allylatlon, crotylatlon, and clnnamylatlon reactions with chlral allylchlorosllanes. The hydrazones are readily and Inexpensively prepared, perform well In the allylatlon chemistry, and more Importantly, the product hydrazldes may be smoothly reduced by Pd(OH)2catalyzed hydrogenation to reveal the corresponding amine products.
