1207948-69-3Relevant academic research and scientific papers
Gold catalysis: Enantiotopos selection
Hashmi, A. Stephen K.,Hamzie, Melissa,Rominger, Frank,Bats, Jan W.
, p. 13318-13322+13274 (2009)
"Chemical Equation Presented" Selecting one out of two enantiotopic alkynes: A furan-diyne substrate with enantiotopic alkynyl groups was prepared and the gold-catalyzed cyclo isomerization by a series of different chiral cationic gold(I) complexes was in
Gold catalysis: Efficient 1,3-induction with diastereotopic homopropargyl alcohols in the phenol synthesis
Hashmi, A. Stephen K.,Hamzic, Melissa,Rudolph, Matthias,Ackermann, Martin,Rominger, Frank
experimental part, p. 2469 - 2481 (2010/03/25)
Furans with diastereotopic alkynyl groups were prepared and then converted to anellated phenols in gold-catalyzed reactions. In all cases a highly diastereoselective reaction was observed. The stereochemical outcome of the 1,3-induction could be assigned
