1207980-32-2Relevant academic research and scientific papers
Cobalt-catalyzed isomerization of 1-alkenes to (E)-2-alkenes with dimethylphenylsilylmethylmagnesium chloride and its application to the stereoselective synthesis of (E)-alkenylsilane
Kobayashi, Tsuneyuki,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 1078 - 1083 (2010/04/23)
Treatment of 1-alkenes with dimethylphenylsilylmethylmagnesium chloride in the presence of a cobalt-NHC complex in dioxane at 50°C or higher provides the corresponding (E)-2-alkenes selectively. The isomerization is applicable to the stereoselective synth
