1207985-10-1Relevant articles and documents
Chemoselectivity of the Ru-catalyzed cycloisomerization reaction for the synthesis of dihydropyrans; application to the synthesis of L-forosamine
Zacuto, Michael J.,Tomita, Daisuke,Pirzada, Zainab,Xu, Feng
, p. 684 - 687 (2010)
Chemical Equation presented The chemoselectivity of a Ru-catalyzed cycloisomerization reaction has been established. The preference for O- capture of the vinylidene Intermediate allows for the synthesis of 4-aminodihydropyrans that are valuable synthetic Intermediates. The synthetic utility of these structures has been demonstrated in the synthesis of L-forosamine.