1208003-68-2Relevant academic research and scientific papers
Synthesis of ligands based on 4H-imidazoles and pyridine subunits: Selective complexation and bathochromically absorbing complexes
Blumhoff, Joerg,Beckert, Rainer,Rau, Sven,Losse, Sebastian,Matschke, Martin,Guenther, Wolfgang,Goerls, Helmar
, p. 2162 - 2169 (2009)
New multifunctional ligands based on the combination of 4H-imidazoles with pyridine subunits have been synthe-sised. The long wavelength absorptions originating from the merocyanine-chromophore can be shifted towards the near infrared (MR) region by introduction of additional auxochromic groups. Due to different complexation spheres these hybrid-ligands form the requirements for the construction of heterobimetallic complexes. In addition, the hybrid ligands are redox active compounds showing two separated fully reversible reductions.
