120818-09-9

Basic information

• Product Name: pentacarbonyl(chlorodiphenylphosphane)rhenium tetrafluoroborate
• CAS NO: 120818-09-9
• Molecular Weight: 633.702
• Mol File: 120818-09-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: pentacarbonyl(chlorodiphenylphosphane)rhenium tetrafluoroborate(CAS DataBase Reference)
• NIST Chemistry Reference: pentacarbonyl(chlorodiphenylphosphane)rhenium tetrafluoroborate(120818-09-9)
• EPA Substance Registry System: pentacarbonyl(chlorodiphenylphosphane)rhenium tetrafluoroborate(120818-09-9)

Safety Data

• Hazardous Substances Data: 120818-09-9(Hazardous Substances Data)

Upstream product

• 78670-75-4 pentacarbonyl(tetrafluoroborato)rhenium 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 120818-19-1 ((OC)5ReP(C₆H₅)2OC₂H₅)⁽¹⁺⁾*BF₄^(1-) = ((OC)5ReP(C₆H₅)2OC₂H₅)BF₄ 
• 120818-17-9 ((OC)5ReP(C₆H₅)2OCH₃)⁽¹⁺⁾*BF₄^(1-) = ((OC)5ReP(C₆H₅)2OCH₃)BF₄ 

Relevant articles and documents

Metallorganische Lewis-Saeuren. XXXVII. Kationische Pentacarbonyl(phosphan)rhenium-komplexe und deren Reactionen mit Nucleophilen

The raections of pentacarbonyltetrafluoroboratorhenium, (OC)5ReFBF3, with PH3, PPh3, PPh2H, and chlorphosphanes lead to cationic complexes +BF4- (1).Nucleophiles react with the chlorphosphane ligands of 1 to give the ionic complexes +BF4- (R'=OH, OMe, OEt).Reaction of +BF4- with OH- yields the bridged 2+2BF4-, whereas with +BF4- and OH- the complex +BF4- is formed.The azide ion is added to a cis-carbonyl ligand of +BF4- to form the neutral isocyanato complex (OC)4(ClPh2P)ReNCO.The hydroxycarbonyl complexes cis-(OC)4Re(PPh2R)(COOH) are obtained from the reaction of +BF4- (R=Ph, H) with hydroxide.The reactions of + with M(CO)5- (L=PPh3, P(OMe)3, CN-tBu; M=Mn, Re) give the nonacarbonyl dimetal compounds L(OC)4Re-M(CO)5.