120822-01-7Relevant academic research and scientific papers
Visible light-promoted C-H functionalization of ethers and electron-deficient arenes
Devari, Shekaraiah,Shah, Bhahwal Ali
supporting information, p. 1490 - 1493 (2016/01/25)
We have developed the visible light mediated C-H arylation of ethers via C(Sp2)-C(Sp3) C-H functionalization involving hydrogen atom transfer (HAT) pathway. The reaction requires no photocatalyst, operates at room temperature, is easy to set up, and is scalable to the gram level. Furthermore, the protocol is easily extendable to other electron deficient arenes such as naphthaquinones and benzothiazoles.
General Reactivity of 2-Lithiobenzothiazole to Various Electrophiles and the Use as a Formyl Anion Equivalent in the Synthesis of α-Hydroxy Carbonyl Compounds
Chikashita, Hidenori,Ishibaba, Megumi,Ori, Keiji,Itoh, Kazuyoshi
, p. 3637 - 3648 (2007/10/02)
The reaction of 2-lithiobenzothiazole with a variety of electrophiles such as aldehydes, ketones, carboxylic esters, lactones, nitriles, and amides afforded the expected addition and substitution products.Trimethylsilyl chloride readily reacted with the b
