1208449-87-9Relevant academic research and scientific papers
Stereoselective synthesis of highly functionalized α-diazo-β- ketoalkanoates via catalytic one-pot mukaiyama-aldol reactions
Zhou, Lei,Doyle, Michael P.
, p. 796 - 799 (2010)
(Chemical Equation Presented) Methyl diazoacetoacetate undergoes zinc triflate catalyzed condensation with a broad selection of aldehydes to produce δ-siloxy-α-diazo-β-ketoalkanoates in good yield, and δ-hydroxy-α-diazo-β-ketoalkanoates are formed with high diastereoselectivity in reactions with α-diazo-β-ketopentanoate promoted by dibutylboron triflate.
