120851-49-2Relevant academic research and scientific papers
Chemistry of Silyl Thioketones. Part 4. 2,4,6-Triaryl-2,4,6-tris(trimethylsilyl)-1,3,5-trithianes from Silyl Thioketones: Crystal Structure of 2,4,6-Triphenyl-2,4,6-tris(trimethylsilyl)-1,3,5-trithiane and Stereochemistry of Desilylation with Fluoride Ion
Bonini, Bianca F.,Mazzanti, Germana,Zani, Paolo,Maccagnani, Gaetano
, p. 1499 - 1502 (2007/10/02)
Silyl thioketones are easily converted into the corresponding trimers (1,3,5-trithianes) under acidic conditions.Both the α-(cis,trans)-and the β-(cis,cis)-isomers were isolated.The β-diastereoisomers predominate over the α-form.The major isomer from the
