120885-46-3

Upstream product

• 90-90-4 (4-bromophenyl)(phenyl)methanone 
• 64881-96-5 tetramethylammonium acetylacetonate 
• 132605-31-3 (E)-(4-Benzoylphenyl)azo-phenyl-sulfide 
• 132555-16-9 (Z)-(4-Benzoylphenyl)azo tert-butyl sulfide 
• 123-54-6 acetylacetone 

Relevant academic research and scientific papers

Arylation of potassium 2,4-pentanedionate via S(RN)1 on diazosulfides

Potassium 2,4-pentanedionate reacts with diazosulfides (E)-1 and (Z)-2 in DMSO to give 3-aryl-2,4-pentanediones 3 via an S(RN)1 process. Advantages and drawbacks of such new access to 3 are reported together with relevant mechanistic implications.

ELECTROCHEMICALLY INDUCED SRN1 AROMATIC NUCLEOPHILIC SUBSTITUTION. MONOANIONS OF β-DICARBONYL AND β-CYANOCARBONYL COMPOUNDS AS NUCLEOPHILES.

Monoanions deriving from β-dicarbonyl or β-cyanocarbonyl compounds can be used as nucleophiles in electrochemically induced SRN1 aromatic nucleophilic substitution with different substrates including cyano or benzoyl substituted aromatic halides and 2-chloroquinoline.