1208986-24-6Relevant articles and documents
Guanidine: Studies on the reaction with ethyl N-(2-amino-1,2-dicyanovinyl) formimidate
De Assuncao, Luisa R.,Marinho, Elina R.,Proenca, Fernanda P.
experimental part, p. 82 - 91 (2010/08/22)
Formimidate 1 was reacted with guanidinium chloride, at room temperature, in the presence of sodium ethoxide and in dilute THF solution, leading to pyrimidine 10 by an unusual intramolecular cyclization process. A different reaction mechanism operated when imidate 1 was combined with guanidinium acetate in nitromethane under reflux. Structure 14 is tentatively assigned to this new product.
