120917-12-6

Basic information

• Product Name: 5,6-epoxy-5,6-dihydroquinoline 1-oxide
• CAS NO: 120917-12-6
• Molecular Weight: 161.16
• Mol File: 120917-12-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5,6-epoxy-5,6-dihydroquinoline 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 5,6-epoxy-5,6-dihydroquinoline 1-oxide(120917-12-6)
• EPA Substance Registry System: 5,6-epoxy-5,6-dihydroquinoline 1-oxide(120917-12-6)

Safety Data

• Hazardous Substances Data: 120917-12-6(Hazardous Substances Data)

Upstream product

• 87707-14-0 1a,7b-dihydrooxireno[2,3-f]quinoline 

Relevant articles and documents

Arene Oxides of Quinoline: Epoxidation, N-Oxidation and N-Methylation Reactions

trans-5,6,7,8-Diepoxy-5,6,7,8-tetrahydroquinoline 5, 5,6-epoxy-5,6-dihydroquinoline 1-oxide 3, 7,8-epoxy-7,8-dihydroquinoline 1-oxide 4 and trans-5,6,7,8-diepoxy-5,6,7,8-tetrahydroquinoline 6 have been formed by oxidation of the corresponding arene oxides of quinoline, 5,6-epoxy-5,6-dihydroquinoline 1 and 7,8-epoxy-7,8-dihydroquinoline 2.The cis-diepoxides, cis-5,6,7,8-diepoxy-5,6,7,8-tetrahydroquinoline 8 and cis-5,6,7,8-diepoxy-5,6,7,8-tetrahydroquinoline 1-oxide 9 were both obtained by a stepwise synthesis from 7,8-epoxy-7,8-dihydroquinoline 2 via the bromohydrin 7.N-Methylation of 5,6-epoxy-5,6-dihydroquinoline 1 and 7,8-epoxy-7,8-dihydroquinoline 2 with methyl trifluoromethanesulfonate yielded the corresponding N-methylquinolinium arene oxide salts 10 and 11.