1209465-54-2Relevant academic research and scientific papers
New, simple synthetic route to functional mono-and biferrocenes
Diallo, Abdou Khadri,Ruiz, Jaime,Astruc, Didier
, p. 1913 - 1920 (2010)
Visible-light photolysis using a simple 100 W lamp of the readily available precursors [(η 5-C5H4R)Fe(η 6-toluene)]-[PF6] (R = H, Me, Cl, COMe, CO2H, CO2Me, CO2CH2CCH, CONHCH2Ph, NHCH2Ph), or the bimetallic precursor [(μ 2, η 5, η '5-Fv)Fe2(η 6-toluene) 2][PF6]2 (Fv = fulvalene) in the presence of a substituted cyclopentadienyl salt C5H4R0M (R0 = COCH 3, CO2 CH3, PPh2, SiMe 2CH2Cl; M = Li or Na) or the dicyclopentadienyl salt 1, 4-C6H4-(CH2C5H4) 2Na2 in dichloromethane, acetonitrile, or tetrahydrofuran under ambient conditions selectively yields 15 functional mono-and biferrocenes.
