121012-26-8

Basic information

• Product Name: Methyl (E,5R,6R)-5,7-bis(benzyloxy)-6-<(methylsulfonyl)oxy>-3-heptenoate
• CAS NO: 121012-26-8
• Molecular Weight: 448.537
• Mol File: 121012-26-8.mol

Chemical Properties

• CAS DataBase Reference: Methyl (E,5R,6R)-5,7-bis(benzyloxy)-6-<(methylsulfonyl)oxy>-3-heptenoate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl (E,5R,6R)-5,7-bis(benzyloxy)-6-<(methylsulfonyl)oxy>-3-heptenoate(121012-26-8)
• EPA Substance Registry System: Methyl (E,5R,6R)-5,7-bis(benzyloxy)-6-<(methylsulfonyl)oxy>-3-heptenoate(121012-26-8)

Safety Data

• Hazardous Substances Data: 121012-26-8(Hazardous Substances Data)

Upstream product

• 917-54-4 methyllithium 
• 104778-68-9 (E)-(4S,5R,6R)-5,7-Bis-benzyloxy-4,6-bis-methanesulfonyloxy-hept-2-enoic acid methyl ester 

Relevant articles and documents

Very High Chemoselective, Regioselective, and E-Stereoselective 1,3-Chirality Transfer Involving Reaction of Acyclic (E)- and (Z)-γ-Mesyloxy α,β-Enoates and Organocyanocopper-Trifluoroborane Reagents. Efficient Synthetic Routes to Functionalized Chiral α-

Reaction of γ-mesyloxy (E)- or (Z)-α,β-enoates with Me2Cu(CN)Li2*BF3 (prepared from MeLi-LiI in ether), MeCu(CN)Li*BF3 (prepared from MeLi-LiBr in ether), and RCu(CN)Li*BF3 (R = Et, n-Pr, n-Bu) in tetrahydrofuran or mixed solvents involving tetrahydrofura