1210433-75-2Relevant academic research and scientific papers
An acyl-claisen approach to tetrasubstituted tetrahydrofuran lignans: Synthesis of fragransin A2, talaumidin, and lignan analogues
Rye, Claire E.,Barker, David
, p. 3315 - 3319 (2009)
A simple and stereocontrolled synthesis of racemic 2,3,4,5-tetrasubstituted tetrahydrofurans was achieved from acyl-Claisen derived syn-disubstituted amides. Georg Thieme Verlag Stuttgart New York.
Cyclization-endoperoxidation cascade reactions of dienes mediated by a pyrylium photoredox catalyst
Gesmundo, Nathan J.,Nicewicz, David A.
supporting information, p. 1272 - 1281 (2014/06/24)
Triarylpyrylium salts were employed as single electron photooxidants to catalyze a cyclization-endoperoxidation cascade of dienes. The transformation is presumed to proceed via the intermediacy of diene cation radicals. The nature of the diene component was investigated in this context to determine the structural requirements necessary for successful reactivity. Several unique endoperoxide structures were synthesized in yields up to 79%.
