1211323-42-0

Basic information

• Product Name: (2S,3R)-2-(benzyloxy)-3-methoxypent-4-enoic acid
• Synonyms: (2S,3R)-2-(benzyloxy)-3-methoxypent-4-enoic acid
• CAS NO: 1211323-42-0
• Molecular Weight: 236.268
• Mol File: 1211323-42-0.mol

Chemical Properties

• CAS DataBase Reference: (2S,3R)-2-(benzyloxy)-3-methoxypent-4-enoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-2-(benzyloxy)-3-methoxypent-4-enoic acid(1211323-42-0)
• EPA Substance Registry System: (2S,3R)-2-(benzyloxy)-3-methoxypent-4-enoic acid(1211323-42-0)

Safety Data

• Hazardous Substances Data: 1211323-42-0(Hazardous Substances Data)

Upstream product

• 1211323-63-5 (2S,3R)-2-(benzyloxy)-3-methoxypent-4-enal 

Downstream Products

• 1211323-98-6 (S)-((3R,6S,8R,10S,12S,Z)-3-(benzyloxymethyl)-10,12-bis(tert-butyldimethylsilyloxy)-8-methoxy-5,11,11-trimethylpentadeca-4,14-dien-6-yl) 3,3,3-trifluoro-2-methoxy-2-phenylpropanoate 
• 1466415-15-5 (3S,4R,8R,10S,12S,14S)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradecan-2-one 
• 1466415-14-4 (3S,4R,8R,10S,12S,14S,E)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-dihydroxy-4,12-dimethoxy-9,9-dimethyl-1-oxacyclotetradec-5-en-2-one 
• 1466415-13-3 (3S,4R,8R,10S,12R,14S,E)-3-(benzyloxy)-14-((R,Z)-4-(benzyloxymethyl)hex-2-en-2-yl)-8,10-bis(tert-butyldimethylsilyloxy)-4,12-dimethoxy-9,9-dimethyl-1-oxacyclo-tetradec-5-en-2-one 
• 1466415-12-2 (2S,3R)-((3R,6S,8R,10S,12R,Z)-3-(benzyloxymethyl)-10,12-bis(tert-butyldimethylsilyloxy)-8-methoxy-5,11,11-trimethylpentadeca-4,14-dien-6-yl) 2-(benzyloxy)-3-methoxypent-4-enoate 

Relevant articles and documents

Stereoselective synthesis of a monocyclic peloruside A analogue

Chemical Equation Presentation The stereoselective synthesis of the monocyclic peloruside A analogue 4 has been achieved, following a new efficient approach for the introduction of the side chain, involving a late-stage addition of vinyl lithium species 7a to aldehyde 8. Further key steps are a highly diastereoselective allyltitanation reaction and a RCM-based macrocyclization.