121137-17-5

Basic information

• Product Name: N-benzoyl-3-nitrovaline methyl ester
• CAS NO: 121137-17-5
• Molecular Weight: 280.28
• Mol File: 121137-17-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzoyl-3-nitrovaline methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzoyl-3-nitrovaline methyl ester(121137-17-5)
• EPA Substance Registry System: N-benzoyl-3-nitrovaline methyl ester(121137-17-5)

Safety Data

• Hazardous Substances Data: 121137-17-5(Hazardous Substances Data)

Upstream product

• 79-46-9 2-nitropropane 
• 101649-82-5 N-benzoyl-2-bromoglycine methyl ester 

Downstream Products

• 14599-03-2 methyl 2-benzamido-3-methylbutanoate 
• 26924-22-1 methyl 2-benzamido-3-methylbut-2-enoate 

Relevant articles and documents

Reaction of N-Benzoyl-2-bromoglycine Methyl Ester with Deprotonated Nitroalkanes: Synthesis of β-Nitro and α,β-Dehydro Amino Acid Derivatives

N-Benzoyl-2-bromoglycine methyl ester (1) reacted with the alkyl nitronates (2a-e) to give the corresponding β-nitro amino acid derivatives (4a-e).Elimination reactions of (4a-d) afforded the α,β-dehydro amino acid derivatives (5a-d).Treatment of the β-nitrovaline derivative (4b) with tributyltin hydride gave the valine derivative (8).Reduction of the β-nitroalanine derivative (4a) gave the β-aminoalanine derivative (9), characterized by hydrolysis to 2,3-diaminopropionic acid hydrochloride