1211565-68-2Relevant academic research and scientific papers
Nickel-catalyzed regioselective carbomagnesation of methylenecyclopropanes through a site-selective carbon-carbon bond cleavage
Terao, Jun,Tomita, Masahiro,Singh, Surya Prakash,Kambe, Nobuaki
supporting information; experimental part, p. 144 - 147 (2010/03/30)
chemical equation presented Unwringing the ring: Methylenecyclopropanes reacted with vinyl and aryl Grignard reagents in the presence of a nickel catalyst to afford vinyl- and arylmagnesation products, respectively, through a selective C - C bond cleavage (see scheme). The reaction provides a new method for the preparation of substituted homoallyl and allyl Grignard reagents.
