1211566-58-3Relevant articles and documents
Synthesis of Chiral Vicinal Diamines by Silver(I)-Catalyzed Enantioselective Aminolysis of N-Tosylaziridines
Chai, Zhuo,Yang, Pei-Jun,Zhang, Hu,Wang, Shaowu,Yang, Gaosheng
, p. 650 - 654 (2017/01/07)
The kinetic resolution of 2-aryl-N-tosylaziridines and the asymmetric desymmetrization of meso-N-tosylaziridines by ring openings with various primary and secondary anilines, and aliphatic amines as nucleophile have been realized by using a single silver(I)/chiral diphosphine complex as catalyst for the first time. The simple starting materials, broad scope, and easy scalability render this protocol a practical way to chiral vicinal diamine derivatives.
Physical organic study of structure-activity-enantioselectivity relationships in asymmetric bifunctional thiourea catalysis: Hints for the design of new organocatalysts
Li, Xin,Deng, Hui,Zhang, Bo,Li, Jiuyuan,Zhang, Long,Luo, Sanzhong,Cheng, Jin-Pei
supporting information; experimental part, p. 450 - 455 (2010/06/22)
The first pKa scales for chiral thiourea catalysts and their correlations with the corresponding parameters of the bifunctional catalysis was reported. Twenty chiral thiourea-tertiary amine compounds were synthesized and electronic variations w
