121190-38-3Relevant academic research and scientific papers
mCPBA-mediated dioxygenation of unactivated alkenes for the synthesis of 5-imino-2-tetrahydrofuranyl methanol derivatives
Deng, Xiaojun,Zhang, Luwen,Liu, Huixia,Bai, Yu,He, Wei
, (2020/11/24)
A mCPBA-mediated, metal-free, intramolecular dioxygenation reaction of unactivated alkenes is reported. In the presence of m-chlorobenzoic peracid, different unsaturated amide substrates could be cyclized via epoxide intermediates, producing the corresponding 5-imino-2-tetrahydrofuranyl methanol products in up to 94% yield at room temperature.
THERMAL O -> C REARRANGEMENT OF N-PHENYL-ALLYLIMIDATES
Metz, P.,Mues, C.
, p. 6841 - 6854 (2007/10/02)
Properly substituted N-phenyl-allylimidates 1 are shown to undergo preferential O -> C sigmatropic rearrangement on heating.The diastereoselectivity of this reaction resembles the one observed in ortho ester Claisen rearrangements.
