12120-03-5

Basic information

• Product Name: IrH(CO)F(P(C₆H₅)3)2Cl
• CAS NO: 12120-03-5
• Molecular Weight: 800.271
• Mol File: 12120-03-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: IrH(CO)F(P(C₆H₅)3)2Cl(CAS DataBase Reference)
• NIST Chemistry Reference: IrH(CO)F(P(C₆H₅)3)2Cl(12120-03-5)
• EPA Substance Registry System: IrH(CO)F(P(C₆H₅)3)2Cl(12120-03-5)

Safety Data

• Hazardous Substances Data: 12120-03-5(Hazardous Substances Data)

Upstream product

• 59246-46-7 bis(triphenylphosphine)carbonyliridium(I) chloride 
• 1493-02-3 formyl fluoride 

Relevant articles and documents

THE REACTION OF FORMYL FLUORIDE WITH TRANSITION METAL COMPLEXES

Formyl fluoride reacts with metal carbonyl anions in a manner similar to acetic formic anhydride.Although formyl complexes may have been formed as unstable intermediates, no neutral formyl complexes could be isolated but rather the expected decomposition products, the metal carbonyl hydrides or dimers, were produced.The attempted oxidative addition of formyl fluoride to various coordinately unsaturated metal complexes also did not result in the formation of formyl derivatives.HF adducts were obtained from the reaction of Ir(CO)Cl(PR3)2 or M(PPh3)4 (M=Pt or Pd) with formyl fluoride whereas Ru(NO)Cl(PPh3)2 and Rh(PPh3)3Cl give the CO complexes Ru(NO)(CO)Cl(PPh3)2 and Rh(CO)Cl(PPh3)2, respectively.