121232-79-9Relevant articles and documents
Synthesis and X-ray Structure of a Nine-Membered Heterocycle Containing Niobium and Oxidic and Nitridic Structural Elements
Roesky, Herbert W.,Liebermann, Johannes,Noltemeyer, Mathias,Schmidt, Hans-Georg
, p. 1641 - 1644 (2007/10/02)
(Me3SiN=PPh2CH2)2 (1) reacts with NbCl5 to form (H2CPPh=NNbCl4)2 (2).The reaction of 2 with THF yields the nine-membered metallaheterocycle (3).Simultaneously, (ClCH2CH2)2 is produced.The X-ray structure of 3 is reported. - Key Words: Metallaheterocycles/ Niobium heterocycles