121237-83-0

Basic information

• Product Name: (2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-pent-4-enyloxymethoxymethyl-tetrahydro-pyran
• Synonyms: (2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-pent-4-enyloxymethoxymethyl-tetrahydro-pyran
• CAS NO: 121237-83-0
• Molecular Weight: 562.703
• Mol File: 121237-83-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-pent-4-enyloxymethoxymethyl-tetrahydro-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-pent-4-enyloxymethoxymethyl-tetrahydro-pyran(121237-83-0)
• EPA Substance Registry System: (2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-methoxy-6-pent-4-enyloxymethoxymethyl-tetrahydro-pyran(121237-83-0)

Safety Data

• Hazardous Substances Data: 121237-83-0(Hazardous Substances Data)

Upstream product

• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 98486-13-6 4-pentenyloxymethylchloride 

Downstream Products

• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 

Relevant articles and documents

PROTECTING GROUPS THAT INCORPORATE A 4-PENTENYL ACETAL MOIETY CAN BE CLEAVED UNDER NEUTRAL CONDITIONS

Alcohols can be protected as their 4-pentenyloxymethyl (POM) ethers, and regenerated therefrom by treatment with NBS in CH3CN/H2O.Ketones and aldehydes are converted into ketals by reaction with 5-hexen-1,2-diol.Regeneration occurs by treatment with NBS or Hg(OAc)2 in aqueous media.Vicinal diols are are converted into acetals by reaction with 4-pentenal.Deprotection is achieved by sequential oxidative and reductive steps.