121250-04-2Relevant articles and documents
Self-disproportionation of enantiomers of isopropyl 3,3,3-(trifluoro)lactate via sublimation: Sublimation rates vs. enantiomeric composition
Yasumoto, Manabu,Ueki, Hisanori,Ono, Taizo,Katagiri, Toshimasa,Soloshonok, Vadim A.
, p. 535 - 539 (2010)
The presented results convincingly demonstrate that self-disproportionation of enantiomers via sublimation is substantially more complex phenomenon then was previously believed. We demonstrate that the racemic form of isopropyl 3,3,3-trifluoro-2-hydroxypr
Enantioselective synthesis of 1,1,1-trifluoroalkan-2-ols by ruthenium- catalyzed hydrogenation
Kuroki, Yoshichika,Asada, Daisuke,Sakamaki, Yuko,Iseki, Katsuhiko
, p. 4603 - 4607 (2007/10/03)
The highly enantioselective synthesis of 1,1,1-trifluoroalkan-2-ols has been achieved by hydrogenating 1,1,1-trifluoroalkan-2-one enol acetates in the presence of chiral ruthenium catalysts. An enol acetate, 2-acetoxy-3,3,3- trifluoro-1-(phenylthio)propen