121335-73-7Relevant academic research and scientific papers
A Convenient Synthesis of 1,3,6-Dioxazocine, 1,3,7-Dioxazocine, 1,3,8-Dioxazecine and 1,3-Dioxa-6,10-diazadodecane
Krakowiak, Krzysztof E.,Kotelko, Barbara,Bradshaw, Jerald S.,Dalley, N. Kent
, p. 1327 - 1330 (2007/10/02)
A series of perhydro heterocycles of eight to ten ring members containing one nitrogen and two oxygen atoms has been prepared.These include four 1,3,6-dioxazocines, and 1,3,7-dioxazonine and one 1,3,8-dioxazecine.A twelve-membered ring containing two oxygen and two nitrogen atoms was also prepared.An X-ray structure of one of the 1,3,6-dioxazocines, 5, was determined.This compound crystallized in the orthorhomic space group Pccn with a = 25.922(15) Angstroem, b = 12.150(4) Angstroem and C = 9.342(4) Angstroem.Two of the 1,3,6-dioxazocines have the benzylidine acetal structure which will hydrolyze to give benzaldehyde.
