121352-48-5Relevant academic research and scientific papers
Ni-catalyzed borylative Diene-Aldehyde coupling: The remarkable effect of P(SiMe3)3
Cho, Hee Yeon,Morken, James P.
supporting information; experimental part, p. 7576 - 7577 (2010/07/08)
The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio- and stereoselective fashion employing a stoichiometric amount of bis(pinacolato)diboron. In the presence of P(SiMe3)3, this reductive coupling furnishes allyl boronic esters which are regioisomeric to those obtained with PCy3 as the ligand. The coupling product may be subject to oxidation, which furnishes the derived 1,3-diol, or allylation with an additional aldehyde, which furnishes the derived 1,6-diol in a stereoselective fashion.
Oxygenation of Substituted Vinylcyclopropanes: Preparative and Mechanistic Studies
Feldman, Ken S.,Simpson, Robert E.
, p. 4878 - 4886 (2007/10/02)
1-Vinylcyclopropanes bearing phenyl, vinyl, or ester substituents at C(2) of the cyclopropyl ring or alkyl groups at C(1) of the vinyl moiety were subjected to phenylthio or phenylseleno radical catalyzed oxygenation to furnish the corresponding substitut
