121362-18-3Relevant academic research and scientific papers
SPIN TRAPPING STUDIES OF PEROXYL RADICALS. DETECTION OF THE REACTIVE INTERMEDIATES FOR OXIDATION GENERATED FROM O2-. AND SULFONYL, SULFINYL AND PHOSPHORYL CHLORIDES
Kim, Yong Hae,Lim, Sang Chul,Hoshino, Mikio,Ohtsuka, Yasuo,Ohishi, Takeshi
, p. 167 - 170 (1989)
The spin trapping studies by ESR have demonstrated that O2-. efficiently reacts with 2-nitrobenzenesulfonyl chloride, 2-nitrobenzenesulfinyl chloride, and diphenylphosphoryl chloride, to result in the formation of their peroxyl radicals, some of which have been key intermediates for site-selective oxidation of certain organic molecules and argued whether they exist as anion and/or radical form.
