12138-21-5Relevant articles and documents
Synthesis, structure, and optical properties of CsU2(PO 4)3
Oh, George N.,Ringe, Emilie,Van Duyne, Richard P.,Ibers, James A.
, p. 124 - 129 (2012)
CsU2(PO4)3 was synthesized in highest yield by the reaction in a fused-silica tube of U, P, and Se in a CsCl flux at 1273 K. It crystallizes with four formula units in space group P21/n of the monoclinic system in a new structure type. The structure of CsU 2(PO4)3 is composed of U and Cs atoms coordinated by PO43- units in distorted octahedral arrangements. Each U atom corner shares with six PO43- units. Each Cs atom face shares with one, edge shares with two, and corner shares with three PO43- units. The structure shares some features with the sodium zirconium phosphate structure type. X-ray powder diffraction results demonstrate that the present CsU2(PO 4)3 compound crystallizes in a structure different from the previously reported β′- and γ-CsU2(PO 4)3 compounds. CsU2(PO4)3 is highly pleochroic, as demonstrated by single-crystal optical absorption measurements.
Crystal structure and magnetic properties of the hexagonal uranium dichalcogenides γUS2 and γUSe2
Daoudi,Levet,Potel,Noel
, p. 1213 - 1218 (1996)
The crystal structure of the hexagonal uranium disulfide γUS2 (hexagonal P62m, a = 7.236(2) A, c = 4.062(1) A, γ = 120°) has been determined from single crystal X-ray diffraction data and confirmed by Rietveld refinements from X-ray powder diffraction intensities of the isostructural selenide γUSe2 (a = 7.6328(3) A, c = 4.1897(2) A, γ = 120°). They crystallize with the anti-Fe2P-type structure. The sulfide γUS2 exhibits weak ferromagnetism below ≈10 K, and the selenide is a ferromagnet with a Curie temperature of ≈20 K and an ordered moment of 0.72 μB/U under 20 kGauss.
Beck, Horst P.,Dausch, Wilma
, p. 32 - 39 (1989)
High-pressure X-ray diffraction study of ThOS and UOSe by synchrotron radiation
Gensini, M.,Gering, E.,Benedict, U.,Gerward, L.,Olsen, J. Staun,Hulliger, F.
, p. L9 - L12 (1991)
High-pressure X-ray diffraction studies were performed on ThOS up to 43.3 GPa and on UOSe up to 47.5 GPa, at room temperature, using a diamond anvil cell and synchrotron radiation. The tetragonal structure (P4/nmm) of these compounds was retained over the whole pressure range. The bulk modulus B0 and its pressure derivative B′0 were determined for each compound.