121386-94-5Relevant academic research and scientific papers
Reaction of organocuprate reagents with protected 1,2-anhydro sugars. Stereocontrolled synthesis of 2-deoxy-C-glycosyl compounds
Bellosta,Czernecki
, p. 275 - 284 (2007/10/02)
The reaction of protected 1,2-anhydro-α-D-gluco- and β-D-manno-pyranoses with alkyl and phenyl organocuprates afforded the corresponding C-glycosyl compounds in acceptable to high yield. Complete stereocontrol was obtained, leading respectively to the β-D or the α-D anomer. With the perbenzylated manno derivative, deoxygenation at C-2 was achieved in high yield, affording 2-deoxy-α-D-C-glycosyl compounds.
Stereocontrolled Synthesis of C-Glycosides by Reaction of Organocuprates with Protected 1,2-Anhydro Sugars, and their Transformation into 2-Deoxy-C-glycosides
Bellosta, Veronique,Czernecki, Stanislas
, p. 199 - 200 (2007/10/02)
The reaction of protected 1,2-anhydro sugars with organocuprates provides a new stereocontrolled synthesis of C-glycosides, the deoxigenation of which affords 2-deoxy-C-glycosides in high yield.
