121399-91-5

Upstream product

• 1445-45-0 Trimethyl orthoacetate 
• 121399-89-1 (E)-1-Benzyloxy-7-(tetrahydro-pyran-2-yloxy)-hept-3-en-2-ol 
• 60656-87-3 benzyloxyacetoaldehyde 
• 85168-38-3 5-lithio-4-pentyn-1-ol tetrahydropyranyl ether 

Downstream Products

• 121399-92-6 (E)-6-Benzyloxy-3-(3-hydroxy-propyl)-hex-4-enoic acid methyl ester 
• 121399-90-4 4-carboxymethoxymethyl-7-benzyloxy-5-heptenal 
• 1211-29-6 methyl jasmonate 

Relevant academic research and scientific papers

INTRAMOLECULAR ENE APPROACH TO STEREOCONTROLLED SYNTHESIS OF CYCLOPENTANOIDS

A new and stereoselective approach to cyclopentanoid synthesis is described.The key step is the thermal intramolecular ene reaction of 4-carboxymethyl-7-benzyloxy-5-heptanal, prepared by the Claisen rearrangement, to afford 2,3-disubstituted cyclopentanol derivative in a highly stereoselective fashion.