1214268-50-4Relevant articles and documents
One-pot synthesis of linearly fused n-heterocyles from their angular analogues and studies of their redox and electrochromic properties
Sinan, Mominul,Ghosh, Kumaresh,Goswami, Sreebrata
, p. 2065 - 2068 (2010)
Chemical Equation Presented In an unusual chemical transformation, the angular heterocyclic compound [1]ClO4, upon reaction with a primary aromatic amine, is transformed to a linear heterocyclic compound 3 via the angular intermediate [2]ClO4 in one pot. Characterization of the compounds was primarily achieved by 1H and 13C NMR and mass spectral data. Analyses of single-crystal X-ray structures of the representative compounds confirmed, their identities. These compounds exhibit notable spectral and redox properties. Their redox behavior is followed by spectral characterization of the electro-generated radicals. Electrochromic properties of the reference compounds are also explored.
