1214756-34-9Relevant academic research and scientific papers
Silver-Mediated Trifluoromethylthiolation-Iodination of Arynes
Zeng, Yuwen,Hu, Jinbo
, p. 856 - 859 (2016)
(Chemical Equation Presented). A one-pot trifluoromethylthiolation-iodination of arynes with trifluoromethylthiosilver (AgSCF3) and 1-iodophenylacetylene is described. This protocol allows rapid construction of o-trifluoromethylthiolated arene building blocks in moderate yields. These products were found to be excellent precursors for Yagupolskii-Umemoto-type electrophilic trifluoromethylation reagents.
TRIFLUOROMETHYLTHIOPHENIUM DERIVATIVE SALT, METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING TRIFLUOROMETHYL-CONTAINING COMPOUNDS USING THE SAME
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Page/Page column 18, (2012/06/01)
A trifluoromethylthiophenium derivative salt useful as synthetic intermediates for pharmaceuticals and agrochemicals, a method for producing the same, and a method for producing trifluoromethyl-containing compounds using the same are provided. An S-(trifl
Efficient access to extended yagupolskii-umemoto-type reagents: Triflic acid catalyzed intramolecular cyclization of ortho- ethynylaryltrifluoromethylsulfanes
Matsnev, Andrej,Noritake, Shun,Nomura, Yoshinori,Tokunaga, Etsuko,Nakamura, Shuichi,Shibata, Norio
supporting information; experimental part, p. 572 - 576 (2010/04/05)
(Figure Presented) King of the ring: S-(trifluoromethyl)benzo[b]thiophenium salts 1, as analogues of Yagupolskii-Umemoto type reagents, were synthesized by novel triflic acid catalyzed intramolecular cyclization of ortho- ethynylaryltrifluoromethylsulfane
