12150-75-3Relevant academic research and scientific papers
Cycloaddition of Carbon Disulfide to the Azide Ligands of (Ph3P)2Pd(N3)2 and (2-)
Fehlhammer, Wolf Peter,Beck, Wolfgang
, p. 546 - 548 (2007/10/02)
(Ph3P)2Pd(N3)2 reacts with CS2 by 1,3-dipolar cycloaddition to give the thiatriazoline-5-thionato complex (Ph3P)2Pd(N3CS2)2.From the reaction of 2 with CS2, the isothiocyanato complex 2 has been isolated, and the intermediate thiatriazoline-5-thionato complex 2 could be detected by its electronic spectrum. - Keywords: Thiatriazolinethionato Complexes, Isothiocyanato Complexes, Palladium(II), Cobalt(III)
