1215016-41-3

Upstream product

• 501-53-1 benzyl chloroformate 
• 1381886-41-4 methyl (S)-3-methyl-2-((R)-tridec-1-en-4-ylamino)butanoate 
• 1381886-43-6 (S)-3-methyl-2-((R)-tridec-1-en-4-ylamino)butan-1-ol 
• 112-31-2 caprinaldehyde 
• 112-30-1 1-Decanol 
• 1112145-09-1 (S,E)-N-decylidene-2-methylpropane-2-sulfinamide 

Downstream Products

• 1215016-39-9 C₂₁H₃₅NO₄ 
• 1215016-46-8 benzyl [(4S,6S)-4-Hydroxy-2-oxopentadecan-6-yl]carbamate 
• 1215016-37-7 benzyl [(4R,6S)-4-hydroxy-2-oxopentadecan-6-yl]carbamate 
• 1361021-43-3 benzyl N-((S)-1-oxododecan-3-yl)carbamate 

Relevant academic research and scientific papers

Stereocontrolled synthesis of piperidine alkaloids, (-)-241D and (-)-isosolenopsin

Highly diastereocontrolled synthesis of alkaloids, (-)-241D and (-)-isosolenopsin was achieved in 7.7% and 5.3% yields, respectively, using a Barbier-type allylation of a chiral imine and d-proline catalyzed aldol addition reaction of a β-amino aldehyde with acetone as the key steps. The synthesis involves a nine-step sequence using (S)-valinate imine in a Barbier-type allylation for the first time.

(N-tert-butanesulfinyl)imines in alkaloid synthesis: Concise formal syntheses of the dendrobate alkaloid (+)-241D and Its C-4 epimer

Concise formal syntheses of the dendrobate alkaloid (+)-241D and its C-4 epimer are described by means of a highly diastereoselective Barbier-type indium-mediated allylation strategy involving an (S)-(N-tert-butanesulfinyl) imine. Georg Thieme Verlag Stut

Stereoselective synthesis of dendrobate alkaloid (+)-241D and its C-4 epimer

An efficient stereoselective synthesis of dendrobate alkaloid (+)-241D and its C-4 epimer was achieved from the inexpensive, commercially available starting material decanal (10) in an overall yield of 21.9% and 21.1%, respectively. This synthesis utilize