1215087-92-5Relevant academic research and scientific papers
SmI2-coupling reaction of chiral non-racemic α-bromo-α′-sulfinyl ketones with imines: synthesis of enantiomerically pure 2-methyl-3-amino-1-ol moieties
Barbarotto, Marie,Geist, Julie,Choppin, Sabine,Colobert, Francoise
experimental part, p. 2780 - 2787 (2010/03/30)
Chiral non-racemic α-bromo-α′-sulfinyl ketones were shown to react with imines in the presence of SmI2 to give the corresponding 1,3-aminoketo derivatives with good syn-diastereoselectivity. Further reduction of these adducts either with DIBAL-
