1215232-93-1Relevant academic research and scientific papers
Triquinanes: A One-Pot IMDA-tandem metathesis cascade strategy: Ring-closing metathesis (RCM) dominates norbornene ROM!
Nguyen, Natalie N. M.,Leclere, Mathieu,Stogaitis, Nicole,Fallis, Alex G.
, p. 1684 - 1687 (2010)
A general route to linear triquinanes including a formal synthesis of (±)-δ9(12)-capnellene is described. This cascade strategy combines an intramolecular Diels-Alder reaction tandem metathesis protocol to generate the linear cis-anti-cis-tricyclo[6.3.0.0 2,6]undecane skeleton directly. Significantly, the ring-closing-ring-opening-cross-metathesis (RCM-ROM-CM) sequence with our norbornene adducts is the only observed mechanism.
