121560-18-7

Basic information

• Product Name: (3aS,6R,7aR)-1-(cyclohex-1-en-1-ylcarbonyl)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
• Synonyms: (3aS,6R,7aR)-1-(cyclohex-1-en-1-ylcarbonyl)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
• CAS NO: 121560-18-7
• Molecular Weight: 323.456
• Mol File: 121560-18-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3aS,6R,7aR)-1-(cyclohex-1-en-1-ylcarbonyl)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzisothiazole 2,2-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,6R,7aR)-1-(cyclohex-1-en-1-ylcarbonyl)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzisothiazole 2,2-dioxide(121560-18-7)
• EPA Substance Registry System: (3aS,6R,7aR)-1-(cyclohex-1-en-1-ylcarbonyl)-8,8-dimethylhexahydro-3a,6-methano-2,1-benzisothiazole 2,2-dioxide(121560-18-7)

Safety Data

• Hazardous Substances Data: 121560-18-7(Hazardous Substances Data)

Upstream product

• 636-82-8 cyclohexene-1-carboxylic acid 
• 94594-90-8 (2R)-bornane-10,2-sultam 
• 121560-19-8 N-<(2S,3S)-2,3-dimethyl-4-pentenoyl>bornane-10,2-sultam 
• 116195-22-3 N-<(2S,3R)-2,3-dimethylpentanoyl>bornane-10,2-sultam 
• 108462-63-1 N-<(E)-2-methyl-2-pentenoyl>bornane-10,2-sultam 
• 108462-64-2 N-<(E)-2-methyl-2-butenoyl>bornane-10,2-sultam 
• 116195-16-5 N-<(E)-2-methyl-2-heptenoyl>bornane-10,2-sultam 
• 18448-47-0 methyl cyclohex-1-ene-1-carboxylate 

Downstream Products

• 121651-45-4 (1S,2R)-2-methyl-1-cyclohexanecarboxylic acid 
• 1020738-50-4 C₁₇H₂₇NO₅S 
• 1020738-52-6 C₁₇H₂₇NO₅S 
• 121578-32-3 N-<(1S,2R)-2-methyl-1-cyclohexanoyl>bornane-10,2-sultam 

Relevant articles and documents

Diastereoselective ru-catalyzed cross-metathesis-dihydroxylation sequence. An efficient approach toward enantiomerically enriched syn-diols

(Chemical Equation Presented) Sequential catalysis has evolved as a powerful concept within the past years and allows the more efficient use of catalytically active expensive transition metals in organic synthesis. In this paper we present the stereoselective cross-metathesis-dihydroxylation of various olefins with chiral auxiliary substituted acrylamides. The chiral information (i.e., the auxiliary) introduced in the metathesis reactions allows for a stereoselective subsequent RuO4-catalyzed dihydroxylation. The sequence is concluded by an unusual kinetic resolution of the diastereomeric diols obtained in the oxidation reaction. As a consequence a variety of structurally diverse enantiomerically enriched diols are obtained. To the best of our knowledge the results summarized in this paper represent the first highly efficient diastereoselective RuO4-catalyzed oxidation.