121654-07-7

Upstream product

• 108-24-7 acetic anhydride 
• 121654-06-6 O-(3,4,6-Tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-1,5-anhydro-3,4-di-O-benzyl-2-deoxy-D-arabino-hex-1-enopyranose 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 74372-90-0 3,4,6-tri-O-benzyl-D-glucal epoxide 
• 58871-10-6 3,4-di-O-benzyl-D-glucal 
• 142819-21-4 ethyl 2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 

Downstream Products

• 196705-16-5 Acetic acid (2R,3R,4S,5R,6R)-2-((2R,3R,4S,5R,6S)-5-acetoxy-3,4-bis-benzyloxy-6-ethylsulfanyl-tetrahydro-pyran-2-ylmethoxy)-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester 
• 196705-15-4 Acetic acid (2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-6-benzyloxymethyl-2-((2R,3R,4R,5R,6S)-3,4-bis-benzyloxy-6-ethylsulfanyl-5-hydroxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Coupling of glycal derived thioethyl glycosyl donors with glycal acceptors. An advance in the scope of the glycal assembly

Glycals were converted into thioethyl glycosyl donors through 1,2-anhydrosugar intermediates. Various participating groups in the C-2 position were examined for formation of β-glucosyl, β-galactosyl, and α-mannosyl linkages. A number of disaccharides was

On the Direct Epoxidation of Glycals: Application of a Reiterative Strategy for the Synthesis of β-Linked Oligosaccharides

The use of dimethyldioxirane for the first direct epoxidation of glycals is described.The products of such reactions, 1,2-anhydro sugars, are employed in the stereospecific construction of β-linked oligosaccharides.A key element is the use of glycals with