121654-29-3Relevant academic research and scientific papers
2-(2,4-Di-tert-butylphenyl)-1,1-bis(trimethylsilyl)silene and 2-(2,4,6-Tri-tert-butylphenyl)-1,1-bis(trimethylslyl)silene - Two new sterically protected but still unstable silaethenes
Luderer, Frank,Retake, Helmut,Oehme, Harfmut
, p. 15 - 20 (1996)
(2,4-Di-terl-butylphenyl)tris(trimethylsilyl)silylmethanol (1a), prepared by the reaction of tris(trimethylsilyl)silylmagnesium bromide with 2,4-di-tert-butylbenzaldehyde, was deprotonated by treatment with methyllithium in ether at -78°C to give the transient 2-(2,4-di-tert-butylphenyi)-1,1-bis(trimethylsilyljsilene (3a), which dimerizes in a head-to-head fashion with the formation of (E)-/(Z)-3,4-bis(2,4-di-terf-butylphenyl)-1,1,2,2-tetrakis(trimethylsilyl)-l,2- disilacyclobutane (5). Besides 5 an unstable compound 4 was obtained, which was preliminarly assigned as 5,7-di-terf-butyl-l-(2,4-di-fert-butylphenyl)-1,2,3,8a-tetrahydro-2,2,3,3- tetrakis(trime thylsilyl)-1,2-disilanaphthalene (4), the formal [2 + 4] cyclodi-mer of 3a. Compound 4 gradually decomposes to give (E)-/(Z)-5, and is considered to be the kinetically preferred dirner of 3a, which is converted into the thermodynamically stable 5. 2,4,6-Tri-tert-butylbenzaldehyde reacts with tris(trimethylsilyljsilyllithium resulting in the formation of 6,8-ditert-butyl-l,2,3,4-tetrahydro-4,4-dimethyl-2,2-bis(trimethylsilyl)-2- silanaphthalene (6). Compound 6 is the product of the insertion of the Si=C bond into the C-H bond of an o-tertbutyl group of the intermediate 2-(2,4,6-tri-ferf-butylphenyl)l,l-bis{t.rimethylsilyl)silene (3b), which despite extreme steric shielding proved to be still unstable. For compounds (Z)-5 and 6 the results of the X-ray analyses are given.
NEW ASPECTS OF ORGANOSELENIUM COMPOUNDS CONTAINING GROUP 14 ELEMENTS
Okazaki, Renji,Tokitoh, Norihiro,Ishii, Akihiko,Ishii, Naoko,Matsuhashi, Yasusuke,et al.
, p. 49 - 66 (2007/10/02)
The synthesis and reactivities of double bond compounds between Group 14 and Group 16 elements have been reported.Specifically the chemistry of M=X type compounds (C=Se, Ge=S, Sn=S, Sn=Se) are described.
